A mathematical model of the copper plating process in restoration of road transport equipment parts
https://doi.org/10.26518/2071-7296-2024-21-2-270-288
EDN: JYBAKN
Abstract
Introduction. The use of restored parts of motor vehicles makes it possible to reduce the financial costs of repairing equipment. The cost of the restored parts should not exceed 50% of the cost of the new part. Increasing the productivity (deposition rate) of an electrolytic copper coating during the restoration of parts of motor vehicles requires taking into account the technological and economic aspects of the restoration process. The study of the factors (deposition conditions) that most affect the deposition process of the copper coating, the analysis of the experimental results and its statistical processing made it possible to optimize the technology of restoration of copper parts to create the most appropriate deposition modes with maximum productivity, thus reducing the cost of restoration of parts of motor vehicles. The purpose of the research is to develop a mathematical model of the effect of deposition conditions (electrolyte temperature, cathode current density) and electrolyte composition (concentration of copper sulfate and sulfuric acid) on the performance of the deposition process of copper coating, for further development of the most productive technology for restoring collectors of electric motors of motor vehicles.
Materials and methods. The studies on equipment that allows obtaining the necessary data with the required accuracy were carried out. Mathematical processing using modern statistical data processing tools that excluded possible errors, providing to obtain the dependence of factors with the necessary accuracy was carried out.
Results. In the course of studies of copper sulfate electrolytes to obtain an electrolytic copper coating, with the further development of technology for the restoration of automotive parts, it became necessary to determine the effect of deposition conditions – “factors” (cathode current density, electrolyte temperature, copper sulfate concentration, sulfuric acid concentration) on the deposition rate – “response”. It was found that the factor “cathode current density” and the combination of factors “cathode current density” and “sulfuric acid concentration” are the most significant. The deposition conditions in order to obtain the most productive technology for restoring collectors of electric motors of motor vehicles by depositing a copper coating have been optimized. According to the obtained model, the optimal values of the deposition conditions for obtaining the maximum deposition rate are the electrolyte temperature of 35...40 ° C, the cathode current density of more than 5 A/Dm2, the concentration of copper sulfate 200...250 g/l, the concentration of sulfuric acid 40...70 g/l.
About the Authors
A. S. IanutaRussian Federation
Anton S. Ianuta. Senior lecturer of the Transport and Technological machines and Complexes Department
MD-3200, Bender city, Bender Vosstaniya str. 7
G. S. Zadorozhnii
Russian Federation
Grigorii S. Zadorozhnii. Leading specialist of educational and research Renovation of machinery and equipment laboratory
MD-3200, Bender city, Bender Vosstaniya str. 7
Yu. V. Shtephan
Russian Federation
Yurii V. Shtefan. Cand. of Sci., Associate Professor of the Production and Repair of Cars and Road Vehicles Department
125319, Moscow, Leningradskii Prospekt, 64
References
1. Kotomchin A.N., Sinelnikov A.F., Korneychuk N.I. Restoration of machine parts: choice of the method. The Russian Automobile and Highway Industry Journal. 2020; 17(1): 84–97. (In Russ.) https://doi.org/10.26518/2071-7296-2020-17-1-84-97
2. Sinelnikov A.F., Bomeshko E.V., Korneychuk N.I., Ianuta A.S. Electrolytic alloying of iron-chromium during deposition of coatings from a sulfate-chloride electrolyte. IOP Conf. Series: Materials Science and Engineering (14th–16th December 2020, Moscow). Moscow. 2020: 1–9.
3. Kolmykov D.V. Restoration and hardening of automobile parts by galvanic coatings. Chief mechanical engineer. 2010; 10: 33–38. (In Russ.)
4. Ianyta A.S. Investigation of the effect of deposition modes on the structure of an electrolytic binary fe-cr coating obtained from a sulfate-chloride electrolyte. Vestnik Moskovskogo avtomobil’no-dorozhnogo gosudarstvennogo tehnicheskogo universiteta (MADI). 2022; 3(70): 17–21. (In Russ.)
5. Lyakhov E.Yu., Zorin V.A. Increasing the efficiency of operation of road machines and vehicles through the use of repair polymeric materials. Nauka i tehnika v dorozhnoj otrasli. 2021; 1(95): 39–43. (In Russ.) EDN WMKAWS.
6. Lyakhov E.Yu., Zorin V.A. Research of the rheological properties of polymeric composite materials using the finite element method. Vestnik Pridnestrovskogo universiteta. Serija: Fiziko-matematicheskie i tehnicheskie nauki. Jekonomika i upravlenie. 2020; 3(66): 114–119. EDN SZJJOE. (In Russ.)
7. Kotomchin A.N., Sinel’nikov A.F., Korneychuk N.I. Use of wear-resistant chromium plating in the restoration and hardening of automotive parts. Vestnik Moskovskogo avtomobil’no-dorozhnogo gosudarstvennogo tehnicheskogo universiteta (MADI). 2021; 1(64): 11–17. (In Russ.)
8. Kotomchin A.N. Оptimization of the chrome plating bath operation during the restoration of vehicle parts. The Russian Automobile and Highway Industry Journal. 2021; 18(4): 390–405. (In Russ.) https://doi.org/10.26518/2071-7296-2021-18-4-390-405
9. Kotomchin A.N., Korneychuk N.I. Production recommendations for the use of chrome plating electrolyte in the conditions of Pridnestrovian enterprises. World of transport and technological machines. 2021; 3(74): 24–34. (In Russ.) DOI:10.33979/2073-7432-2021-74-3-24-34
10. Kotomchin A.N., Lyakhov E.Yu. Restoration of the parts of the machinery units and assembliesworking under the hydro-abrasive wear. Remont. Vosstanovlenie. Modernizacija. 2019; 5: 8–12. DOI 10.31044/1684-2561-2019-0-5-8-12. EDN EOTTUJ.
11. Kotomchin A.N., Korneychuk N.I. Optimization of electrolysis conditions during the restoration of the valves of the hydraulic distributor p-80 by chrome plating. Vestnik Pridnestrovskogo universiteta. Serija: Fiziko-matematicheskie i tehnicheskie nauki. Jekonomika i upravlenie. 2021; 3(69): 113–119. (In Russ.) EDN PBCCLG.
12. Zadorozhny G.S., Bomeshko E.V., Yanuta A.S. To the question of methods for analyzing the composition of electrolytes for electroplating of iron-based coatings. Gal’vanotehnika i obrabotka poverhnosti. 2023; T. 31, no 2: 4–14. (In Russ.) DOI 10.47188/0869-5326_2023_31_2_4. EDN JMTVUA.
13. Kotomchin A.N., Sinelnikov A.F. Installation for maintaining the operating temperature of electrolytes when restoring machine parts with electroplated coatings. The Russian Automobile and Highway Industry Journal. 2020; 17(4): 500–511. (In Russ.) https://doi.org/10.26518/2071-7296-2020-17-4-500-511
14. Bomeshko E.V., Korneichuk N.I. Electrodeposition of double and ternary alloys based on iron and chromium: theoretical concepts and practical recommendations. Vestnik PGU. 2019; T. 3, no 53: 153–165. (In Russ.) EDN LWYMVB.
15. Korneichuk N.I. Prospects of intensification of machine parts restoration by electrolytic chromium plating. Trudy GOSNITI. 2010; T. 106: 197–203. (In Russ.) EDN SZTTDP.
16. Korneichuk N.I., Erhan F.M., Bomesco E.V. Effect of parameters of periodic current with reverse regulated impulse on the structure and microhardness of electrolytic iron coatings. Vestnik Pridnestrovskogo universiteta. Serija: Fiziko-matematicheskie i tehnicheskie nauki. Jekonomika i upravlenie. 2017; (3)57: 81–87. (In Russ.) EDN YLDAZW.
17. Serebrovsky V.I., Serebrovsky V.V., Safronov R.I., Gnezdilova Y.P. Strengthening alloying of electrodeposited iron. Vestnik Kurskoj GSHA. 2015; 4, 2015: 68–71. (In Russ.)
18. Korneichuk N.I., Lyalyakin V.P. Prospects for the use of industrial methods of restoration of worn machine parts by galvanic and polymer coatings in modern conditions of development of agro-industrial technical service. Trudy GOSNITI. 2018; T. 130: 254–264. (In Russ.)
19. Guryanov G.V., Kisel Yu.E., Lysenko A.N., Obozov A.A. Increasing the wear resistance of parts by electrochemical iron-based alloys. Sel’skij mehanizator. 2017; 2: 34–35. (In Russ.) EDN ZDEDMR.
20. Mukhin V.V. Baurova N.I. Assessment of corrosion resistance of the joints restored with the use of polymer composite materials. Tehnologija metallov. 2022; 10: 39–45. DOI 10.31044/1684-2499-2022-0-1039-45. (In Russ.) EDN VTFHFQ.
21. Mukhin V.V. Methodology of Estimation of Properties of Epoxy Composite Materials Working in Wet Environment. Remont. Vosstanovlenie. Modernizacija. 2022; 7: 35–39. (In Russ.) DOI 10.31044/1684-2561-2022-0-7-35-39. EDN ZAQXKD.
22. Lyakhov E.YU. Modeling of fatigue failure processes of bearing units of the cars restored with polymeric materials. Vestnik Moskovskogo avtomobil’no-dorozhnogo gosudarstvennogo tehnicheskogo universiteta (MADI). 2020; 1(60): 25–30. (In Russ.) EDN FKHJTC.
23. Emelyanov, A.A. Methods of body corrosion protection. Remont. Vosstanovlenie. Modernizacija. 2022; 9: 36–39. DOI 10.31044/1684-2561-2022-0-9-36-39. (In Russ.) EDN TFNOOS.
24. Muhin V.V., Baurova N.I. Investigation of thixotropic properties of dispersed fillers used in the repair of machines. Vestnik Moskovskogo avtomobil’no-dorozhnogo gosudarstvennogo tehnicheskogo universiteta (MADI). 2023; 2(73): 28–32. (In Russ.) EDN TJNKKA.
25. Lanuta A.S., Shtefan Yu.V., Fiodorov V.К., Korneichuk N.I. Electrolytic coating of iron-chromium alloy of sulphate-chloride electrolyte in machine parts recovery process modelling. The Russian Automobile and Highway Industry Journal. 2023; 20(2): 260–276. (In Russ.) https://doi.org/10.26518/2071-7296-2023-20-2-260-276. EDN: CBHVWL
26. Artemchuk V.V., Bosov A.A. Theoretical bases of mathematical modeling of electrolytic coating processes. Vіsnik Dnіpropetrovs’kogo nacіonal’nogo unіversitetu zalіznichnogo transportu іm. akademіka V. Lazarjana. 2007; 15: 52–56.
27. Khlystov, A.V.; Babenko, V.A. Mathematical modeling and optimization of regimes of iron making in “hot” chloride electrolytes on asymmetric current. Vestnik Saratovskogo gosudarstvennogo tehnicheskogo universiteta. (In Russ.) 2004; 4(5): 44–47.
28. Stefan Y.V., Zorin V.A. Methods of identification and assessment of risks in road construction and engineering: a monograph. Moscow: MADI, 2017:136. 29. Stefan Yu.V., Abdullaev A.. R. Mathematical model of cube-shaped crushed stone production technology based on reliability theory. Novye materialy i tehnologii v mashinostroenii. 2023; 37: 132–138. (In Russ.) EDN VFGHLS.
Review
For citations:
Ianuta A.S., Zadorozhnii G.S., Shtephan Yu.V. A mathematical model of the copper plating process in restoration of road transport equipment parts. The Russian Automobile and Highway Industry Journal. 2024;21(2):270-288. (In Russ.) https://doi.org/10.26518/2071-7296-2024-21-2-270-288. EDN: JYBAKN